Introduction Materials of Daily Use
- Materials of daily use include acids, bases, and salts which are widely used in our homes, industries, and laboratories.
- They have different properties, applications, and roles in chemical reactions.
- Caution → We should not taste or touch all substances directly as they may be harmful, corrosive, or poisonous.
Acids
- Definition: Substances that produce hydrogen ions (H⁺/protons) in aqueous solution.
- Taste: Sour.
- Examples: Hydrochloric acid (HCl), Sulphuric acid (H₂SO₄), Citric acid.
Bases
- Definition: Substances that produce hydroxyl ions (OH⁻) in aqueous solution.
- Taste: Bitter; feel soapy.
- Examples: Sodium hydroxide (NaOH), Potassium hydroxide (KOH).
Salts
- Definition: Substances formed by the neutralisation reaction of acid and base.
- Examples: Sodium chloride (NaCl), Copper sulphate (CuSO₄).
Indicator
- Definition: A substance that changes colour in the presence of acids and bases, helping to identify their nature.
- Types: Natural (litmus, red cabbage juice), Synthetic (methyl orange, phenolphthalein).
Table: Colour of Indicators in Acidic, Basic and Neutral Solutions
| Indicator | Acidic Solution | Basic Solution | Neutral Solution |
| Red litmus paper | Remains red | Turns blue | Red |
| Blue litmus paper | Turns red | Remains blue | Blue |
| Methyl orange | Red | Yellow | Orange |
| Phenolphthalein | Colourless | Pink | Colourless |
| Red cabbage juice | Red/pink | Green/blue | Purple |
Acids
Definition
- Substances that release H⁺ ions in aqueous solution and turn blue litmus red.
Types of Acids
- Mineral Acids
- Definition: Strong inorganic acids prepared from minerals.
- Examples: Hydrochloric acid (HCl), Sulphuric acid (H₂SO₄), Nitric acid (HNO₃).
- Organic Acids
- Definition: Weak acids found naturally in plants/animals.
- Examples: Citric acid (citrus fruits), Acetic acid (vinegar), Lactic acid (milk).
Applications of Acids in Daily Life
- Citric acid in food preservation.
- Sulphuric acid in car batteries.
- Acetic acid in vinegar for cooking.
- Hydrochloric acid in digestion in the stomach.
Physical Properties of Acids
- Sour in taste.
- Turn blue litmus red.
- Conduct electricity in aqueous solution.
- Corrosive in nature (can damage skin/metals).
Chemical Properties of Acids (with examples)
- Reaction with Metals → Produces salt + hydrogen gas.
- Zn + 2HCl → ZnCl₂ + H₂↑
- Reaction with Bases (Neutralisation) → Produces salt + water.
- HCl + NaOH → NaCl + H₂O
- Reaction with Carbonates → Produces salt + water + carbon dioxide.
- CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂↑
- Reaction with Metal Oxides → Produces salt + water.
- H₂SO₄ + CuO → CuSO₄ + H₂O
Uses of Acids
Inorganic Acids:
- HCl → Used in cleaning metal surfaces, digestive acid in stomach.
- H₂SO₄ → Used in car batteries, manufacture of fertilizers, detergents.
- HNO₃ → Used in making explosives, fertilizers.
- H₃PO₄ → Used in soft drinks, fertilizers.
Organic Acids:
- Citric acid → Food preservative, sour taste in citrus fruits.
- Acetic acid → Vinegar, used in pickling.
- Lactic acid → Found in curd, used in food industry.
- Tartaric acid → Used in baking powder.
Bases
Definition
- Substances that produce OH⁻ ions in water and turn red litmus blue.
- Examples: NaOH, KOH, NH₄OH.
Strong Bases and Weak Bases
- Strong Bases
- Definition: Completely dissociate into OH⁻ ions in solution.
- Examples: NaOH, KOH.
- Uses: Soap-making, neutralising acids.
- Weak Bases
- Definition: Partially dissociate into OH⁻ ions.
- Examples: NH₄OH, Mg(OH)₂.
- Uses: Medicine (antacids), laboratory uses.
Physical Properties of Bases
- Bitter in taste.
- Soapy/slippery to touch.
- Turn red litmus blue.
- Good conductors of electricity in aqueous solution.
- Corrosive in strong concentrations.
Chemical Properties of Bases (with equations)
- Reaction with Acids (Neutralisation)
- NaOH + HCl → NaCl + H₂O
- Reaction with Non-metal Oxides
- 2NaOH + CO₂ → Na₂CO₃ + H₂O
- Reaction with Ammonium Salts (Releases Ammonia Gas)
- NaOH + NH₄Cl → NaCl + H₂O + NH₃↑
Uses of Bases/Alkalis
- Sodium Hydroxide (NaOH)
- Used in soap-making.
- Paper industry.
- Potassium Hydroxide (KOH)
- Used in making liquid soaps.
- Used in alkaline batteries.
- Ammonium Hydroxide (NH₄OH)
- Used as a cleaning agent.
- Used in fertilizers.
- Calcium Hydroxide (Ca(OH)₂)
- Used in whitewashing walls.
- Used in neutralising acidic soil.
- Magnesium Hydroxide (Mg(OH)₂)
- Used as antacid (milk of magnesia).
- Used in wastewater treatment.
Salts
Definition
- Salts are ionic compounds formed by neutralization of acids and bases.
Types of Salts
- Neutral Salts
- Formed when strong acid reacts with strong base.
- Example: NaCl.
- Neutral because solution is neither acidic nor basic.
- Acidic Salts
- Formed when strong acid reacts with weak base.
- Example: NH₄Cl.
- Acidic due to incomplete neutralization.
- Basic Salts
- Formed when weak acid reacts with strong base.
- Example: Na₂CO₃.
- Basic due to leftover OH⁻ ions.
Physical Properties of Salts
- Crystalline solids.
- Soluble in water (mostly).
- Have definite melting/boiling point.
- Conduct electricity in solution.
- Taste may be salty, bitter, or sour depending on type.
Chemical Properties of Salts
a. Ionization in Water
- NaCl → Na⁺ + Cl⁻
b. Reaction with Acids
- Na₂CO₃ + 2HCl → 2NaCl + H₂O + CO₂↑
c. Reaction with Bases
- NH₄Cl + NaOH → NaCl + NH₃↑ + H₂O
d. Reaction with Active Metals
- Zn + CuSO₄ → ZnSO₄ + Cu
Uses of Salts
- Sodium Chloride (NaCl) → Food seasoning, preservative.
- Sodium Carbonate (Na₂CO₃) → Washing soda, softening hard water.
- Sodium Bicarbonate (NaHCO₃) → Baking soda, antacid.
- Copper Sulphate (CuSO₄) → Fungicide, electroplating, blue vitriol.
Exam Tip: Always remember → Acid + Base → Salt + Water (Neutralization).
Use word equations and balanced chemical equations wherever possible in answers
Comparison: Acids vs Bases vs Salts
| Feature | Acids | Bases/Alkalis | Salts |
| Definition | Substances producing H⁺ ions in solution | Substances producing OH⁻ ions in solution | Formed by neutralisation of acid & base |
| Taste | Sour | Bitter, soapy | Varies (salty, bitter, etc.) |
| Litmus test | Blue → Red | Red → Blue | Mostly neutral (no change) |
| pH range | < 7 | > 7 | ≈ 7 (neutral salts) |
| Examples | HCl, H₂SO₄, Acetic acid | NaOH, KOH, NH₄OH | NaCl, Na₂CO₃, CuSO₄ |
| Common uses | Batteries, digestion, food industry | Soap-making, antacids, fertilizers | Seasoning, electroplating, detergents |
Interesting Facts
- Litmus is a natural dye obtained from lichens.
- Stomach acid (HCl) has pH ~2, strong enough to dissolve metal nails if left for long.
- Baking powder = Sodium bicarbonate + Tartaric acid → used in fluffy cakes.
- Copper sulphate crystals are blue, but turn white when water of crystallisation is removed.
Mnemonics/Memory Aids
- Acids turn Blue litmus Red → “Acid makes B to R” (Think: B-R = Break).
- Bases turn Red litmus Blue → “Base makes R to B” (Think: R-B = Reverse).
- Strong Acid + Strong Base = Neutral Salt (NaCl example).
Summary / Quick Revision
- Acids → Sour, H⁺ producer, corrosive, used in batteries, digestion.
- Bases → Bitter, OH⁻ producer, soapy, used in soap, cleaning, antacids.
- Salts → Neutralisation products, crystalline, wide applications (NaCl, Na₂CO₃, NaHCO₃, CuSO₄).
- Indicators → Litmus, methyl orange, phenolphthalein, red cabbage juice.
- Daily life applications → Preservatives, fertilizers, electroplating, medicines.
- Equations to remember →
- Acid + Metal → Salt + H₂↑
- Acid + Base → Salt + H₂O
- Acid + Carbonate → Salt + H₂O + CO₂↑
- Base + Ammonium salt → Salt + H₂O + NH₃↑
Acid Rain
Definition & Overview
- Acid rain → Rainwater mixed with strong mineral acids such as sulphuric acid (H₂SO₄) and nitric acid (HNO₃) formed in the atmosphere.
- Caused by burning of fossil fuels, volcanic eruptions, industries releasing SO₂, NO₂, CO₂.
- pH of acid rain ≈ < 5.6 (normal rainwater has pH ≈ 5.6 due to dissolved CO₂).
Formation of Acid Rain
- Formation of sulphuric acid
- SO₂ (from burning coal, oil, industries) + O₂ → SO₃
- SO₃ + H₂O → H₂SO₄ (sulphuric acid in rainwater)
- Formation of nitric acid
- N₂ + O₂ → NO (in vehicle engines, lightning)
- NO + O₂ → NO₂
- NO₂ + H₂O → HNO₃ (nitric acid in rainwater)
- Acid rain formation
- Cloud droplets absorb H₂SO₄ and HNO₃ → rain/snow/sleet with acidic pH.
Effects of Acid Rain (4 points)
- Destroys aquatic life → lowers pH of rivers/lakes, kills fish.
- Damages crops & forests → leaches nutrients from soil, harms leaves.
- Corrodes buildings/monuments → dissolves marble (Taj Mahal → “Marble cancer”).
- Affects human health → respiratory problems (asthma, bronchitis).
Control Measures (4 points)
- Reduce fossil fuel use, promote renewable energy.
- Use scrubbers & catalytic converters in industries/vehicles.
- Afforestation (trees absorb CO₂, SO₂, NO₂).
- Awareness & international agreements (e.g., Kyoto Protocol, Paris Agreement).
Soft Water & Hard Water
a. Soft Water
- Definition → Water that easily forms lather with soap.
- Example → Rainwater, distilled water.
- Why called soft? → No dissolved calcium/magnesium salts.
- Features (3):
- Produces lather quickly with little soap.
- Does not form scum.
- Suitable for washing and laundry.
b. Hard Water
- Definition → Water that does not lather easily with soap but forms scum.
- Example → Well water, river water rich in minerals.
- Why called hard? → Contains dissolved Ca²⁺, Mg²⁺ salts.
- Features (3):
- Wastes soap → forms insoluble scum.
- Causes scaling in boilers/pipes.
- Not good for washing, but healthier to drink (contains minerals).
Hardness of Water
a. Temporary Hardness
- Caused by calcium & magnesium bicarbonates (Ca(HCO₃)₂, Mg(HCO₃)₂).
- Why called temporary? → Removed by boiling.
- Causes → Scale deposits in kettles and boilers.
Removal Methods:
i. By boiling → Bicarbonates decompose to insoluble carbonates → settle as precipitate.
ii. Clark’s method → Add slaked lime (Ca(OH)₂) → precipitates bicarbonates as insoluble CaCO₃, Mg(OH)₂.
b. Permanent Hardness
- Caused by sulphates, chlorides, nitrates of Ca²⁺, Mg²⁺.
- Why permanent? → Cannot be removed by boiling.
- Causes → Serious boiler scaling, reduces efficiency.
Removal Methods:
i. By washing soda (Na₂CO₃):
- CaSO₄ + Na₂CO₃ → CaCO₃↓ + Na₂SO₄
- Converts soluble salts to insoluble precipitates.
ii. Permutit method (Ion exchange):
- Water passed through sodium zeolite (Na₂Z).
- Ca²⁺, Mg²⁺ ions exchanged with Na⁺ ions.
- Permanent & efficient method for large-scale water softening.
Alloys (Mixed Metals)
- Alloys → Homogeneous mixtures of two or more metals, or metal + non-metal (like carbon).
- Prepared to improve strength, hardness, resistance, durability compared to pure metals.
Properties of Alloys (4 points)
- Harder than parent metals.
- Resistant to corrosion/rust.
- Sometimes lighter but stronger.
- Better appearance (lustre, color).
Some Common Alloys
- Steel → Iron + Carbon (sometimes Ni, Cr).
- Uses: Construction, tools, vehicles, bridges.
- Brass → Copper + Zinc.
- Uses: Musical instruments, utensils, decorative items.
- Bronze → Copper + Tin.
- Uses: Statues, medals, bells, coins (historical).
- Duralumin → Aluminium + Copper + Manganese + Magnesium.
- Uses: Aircraft, vehicles, machinery (lightweight + strong).
Interesting Facts
- Norway & Canada still face acid rain due to industrial emissions in neighboring countries.
- Soap forms scum in hard water because Ca²⁺ + soap (sodium stearate) → insoluble calcium stearate.
- Bronze Age (historical period) → named after the widespread use of bronze tools.
Mnemonics
- Temporary hardness → Bicarbonates → Boiling removes. (Think: B = Boil).
- Permanent hardness → Sulphates/Chlorides → Soda/Zeolite removes. (Think: P = Permutit).
Quick Revision
- Acid Rain: Caused by SO₂, NO₂ gases → forms H₂SO₄, HNO₃ → damages environment, monuments, health.
- Soft Water: Easily lathers with soap; Hard Water: Contains Ca²⁺, Mg²⁺, causes scum.
- Temporary Hardness: Due to bicarbonates, removed by boiling/Clark’s method.
- Permanent Hardness: Due to sulphates/chlorides, removed by washing soda/Permutit.
- Alloys: Mixtures of metals → stronger, durable. Examples: Steel, Brass, Bronze, Duralumin.
Also Check Out :- Chapter 1 , chapter 2 , chapter 3 , chapter 4 , chapter 5 , chapter 6 , chapter 7 , chapter 8